WebCombination of trifluoroacetic anhydride or trichloroacetic anhydride as dehydrating agents with TMSClO 4 as a Lewis acid afforded desired glycosides in good yields. t … Trimethylsilyl chloride, also known as chlorotrimethylsilane is an organosilicon compound (silyl halide), with the formula (CH3)3SiCl, often abbreviated Me3SiCl or TMSCl. It is a colourless volatile liquid that is stable in the absence of water. It is widely used in organic chemistry. See more TMSCl is prepared on a large scale by the direct process, the reaction of methyl chloride with a silicon-copper alloy. The principal target of this process is dimethyldichlorosilane, but substantial amounts of the … See more TMSCl is reactive toward nucleophiles, resulting in the replacement of the chloride. In a characteristic reaction of TMSCl, the nucleophile is water, resulting in See more
Synthesis of the Tetrasaccharide Repeating Unit from …
WebMay 1, 2015 · The disaccharide units could be coupled with the aid of TMSClO4 as an activator of the diphenyl phosphate leaving group, and global deprotection completed the … WebThis page is a summary of: Novel Dehydrative Glycosylation by Using Acid Anhydride and TMSClO4, Chemistry Letters, January 1999, The Chemical Society of Japan, DOI: 10.1246/cl.1999.27. You can read the full text: Read data privacy act ra 10173 pdf
Novel Dehydrative Glycosylation by Using Acid Anhydride and TMSClO4
WebPublishing platform for digital magazines, interactive publications and online catalogs. Convert documents to beautiful publications and share them worldwide. Title: Nucleoside Analogues Synthesis using Natural Phosphate Doped with I2 (NPI2) in HMDS, Author: Alexander Decker, Length: 5 pages, Published: 2013-06-12 WebDec 1, 2003 · Request PDF On Dec 2, 2003, Beatrice Wagner and others published Catalytic Glycosylation with Rhodium(III)-Triphos Catalysts Find, read and cite all the research you … WebAn unusual solvent effect on the regiochemical outcome (N-9 versus N-7) of guanine glycosylation using Robins' reagent (2-N-acetyl-6-O-diphenylcarbamoylguanine) martocchio 2015